Phase Industry
Phase Industry
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Singapore Commercial Office
sales@phase-industry.com
HPQ 4N to 5N9 • Certified Trace Metrology

Products, Specifications & Quality Assurance

Delivering dependable supply and consistent quality across 4N to 5N9 purity grades. From high-temperature crucible coarse sand to micronized powders, supported by batch-specific ICP-MS Certificate of Analysis (CoA) metrology.

High-Purity Quartz Sand Crystals
Material: High-Purity Quartz (HPQ) · SiO₂

Translucent Crystalline Silica,
Refined to Sub-ppb Purity

  • — SiO₂ ≥ 99.99% (4N) to 99.9999% (5N9)
  • — Total metallic impurities < 1 ppm (5N grades)
  • — Hydroxyl (OH⁻) < 5 ppm for thermal stability
  • — Coarse sand (0.1–0.4 mm) & micronized powder (5–45 µm)
  • — Custom granulometry available on request
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Specification Matrix

High-Purity Quartz (HPQ) Portfolio

Product Grade SiO₂ Purity Typical Sizing (d₅₀ / Mesh) Target Applications
Phase-4N Standard Industrial Grade ≥ 99.99%
Total Impurity < 25 ppm
0.1 mm - 0.4 mm (approx. 40 - 100 mesh) or customized Optical glass, electronic-grade fiberglass (Low-Dk/Ne), high-temperature quartz components.
Phase-4N8 / 5N High-Purity Crucible & Substrate Grade ≥ 99.998%
Total Impurity < 8 ppm
d₅₀: 5 µm - 45 µm or melting sand Quartz crucibles (middle/outer layers), optical substrates, chemical vapor deposition (CVD) equipment.
Phase-5N8 / 5N9 Ultra-Pure Engineered Grade (Up to 5N9) ≥ 99.9998% to 5N9
Total Impurity < 1.5 ppm down to sub-ppm
Tailored per customer specifications High-end quartz crucible inner layers, laser optics, synthetic quartz, specialized optical fiber preforms.
Trace Impurity Suppression

Critical Impurity Suppression & ICP-MS Standard

High-temperature quartz crucible longevity and optical performance depend strictly on suppressing specific deleterious metallic impurities. Our partner facility's multi-stage Asian refining line targets sub-ppm thresholds across all critical elements.

01 / Transition Metals

Iron (Fe) & Heavy Metals

Fe < 0.2 ppm (Sub-ppb in 5N8/5N9)

Transition metals act as carrier recombination centers, degrading efficiency in single-crystal silicon. Multi-stage chemical leaching strips Iron down to baseline thresholds.

Phase-5N8/5N9 limit: ≤ 0.12 ppm
02 / Network Elements

Aluminum (Al) & Titanium (Ti)

Al < 5.0 ppm threshold

Aluminum triggers cristobalite devitrification at 1450°C during silicon ingot pulling. Strict Al suppression inhibits inner crucible wall degradation and particulate shedding.

Phase-5N8/5N9 limit: ≤ 3.80 ppm
03 / Mobile Ions

Alkali Metals (Na, K, Li)

Na + K + Li < 0.5 ppm combined

Alkali ions have high thermal mobility, causing gate oxide breakdown and dielectric threshold voltage drift. Thermal calcination and acid extraction suppress alkali content.

Phase-5N8/5N9 limit: ≤ 0.35 ppm combined
04 / Dopant Elements

Boron (B) & Phosphorus (P)

B + P < 0.1 ppm combined

Boron and phosphorus are electrically active dopant impurities that critically alter the resistivity of silicon wafers. Suppression below detection limits is mandatory for semiconductor and photovoltaic-grade quartz applications.

Phase-5N8/5N9 limit: ≤ 0.05 ppm combined

Typical ICP-MS Trace Element Comparison Matrix

Concentrations expressed in parts per million (ppm by weight) via Inductively Coupled Plasma Mass Spectrometry.

AGILENT 7900 ICP-MS
Element Symbol Impurity Category Standard Commodity HPQ Phase-4N Phase-4N8 / 5N Phase-5N8 / 5N9 Ultra-Pure
Fe (Iron)Transition Metal > 3.00 ppm < 0.90 ppm < 0.35 ppm < 0.12 ppm
Al (Aluminum)Network Former > 25.00 ppm < 14.00 ppm < 6.50 ppm < 3.80 ppm
Ti (Titanium)Refractory Interstitial > 2.50 ppm < 1.20 ppm < 0.50 ppm < 0.20 ppm
Na (Sodium)Alkali Mobile Ion > 1.50 ppm < 0.80 ppm < 0.25 ppm < 0.10 ppm
K (Potassium)Alkali Mobile Ion > 1.20 ppm < 0.70 ppm < 0.20 ppm < 0.08 ppm
Li (Lithium)Light Alkali Ion > 0.80 ppm < 0.50 ppm < 0.15 ppm < 0.05 ppm
Total Metallic Sum12 Elements Combined > 35.00 ppm < 20.00 ppm < 8.00 ppm < 4.50 ppm (Sub-ppm for 5N9)
Thermal Rigidity & Optical Clarity

Hydroxyl (OH⁻) Control (< 5 ppm)

Maintained within strict thresholds (< 5 ppm or custom tailored) to prevent structural deformation and preserve superior UV/IR transmission in fused silica and optical components.

PREVENTION OF CRUCIBLE SAGGING AT 1450°C Hydroxyl radicals break continuous silicon-oxygen network bonds, dramatically lowering high-temperature shear viscosity. Tight OH⁻ suppression preserves structural stability during multi-day silicon crystal growth.
BROAD-SPECTRUM OPTICAL TRANSMISSION Suppresses the fundamental 2.73 µm OH absorption band, enabling superior optical throughput for high-energy laser optics, synthetic quartz ingots, and fiber preforms.
Spectrometry Metrology
FTIR SPECTROMETRY BENCH OH⁻ < 5 ppm
100% Batch Traceability Protocol • Class 1000 Clean Packaging

Every Lot Certified by Agilent 7900 ICP-MS

Detection limits down to 0.01 ppb with 10-year archival retention on every production batch.

Particle Morphology

Particle Size & Granulometry Capabilities

Screening, milling, and ultrasonic air classification calibrated to customer crucible fusion profiles and dielectric resin mixing requirements.

Melting / Crucible Grade (Coarse)

0.1 mm to 0.4 mm range (40 - 100 mesh)

Optimized for fluid dynamics and minimum bubble inclusion during high-temperature fusion.

• Bulk Density: 1.38 - 1.45 g/cm³
• Fusion Behavior: Minimum Gas Entrapment

Micronized / Fine Grade

Controlled d₅₀ down to 5 µm - 45 µm

Designed for precision ceramic fillers, optical slurries, and advanced composite integrations.

• Contamination: Zero Metallic Abrasion
• Particle Sphericity: High Uniformity

Custom Sieve Analysis

Targeted d₁₀, d₅₀, d₉₀ Tolerances

Full flexibility to match your exact d₁₀, d₅₀, d₉₀ and particle cut requirements.

• Measurement: Laser Diffraction Sizing
• Verification: CoA Curve Attached
Morphology Verification

Grain Packing & High-Temperature Fusion Integrity

Under electric vacuum arc melting, quartz particles undergo rapid vitrification. Phase Industry balances particle geometry and packing density to eliminate gas pockets and suppress micro-bubble formation in synthetic silica ingots and crucible walls.

Available packaging: 25 kg multi-wall cleanroom PE bags or 1,000 kg nitrogen-purged super sacks with moisture barrier liners.
Quartz Particle Size Sieve Analysis
B2B Material Evaluations

Request Material Samples & Analytical CoA

Contact our Singapore Commercial Office to configure custom mesh sizing, obtain batch ICP-MS trace element certificates, or arrange evaluation samples for trial runs.

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